Candice Accola and Joe King have called the move resigning after seven years of marriage.
According to Us Weekly, a Vampire Diaries alum, 35, filed for divorce from The Fray member, 41, after posting a photo of a wounded person.
The couple, which is believed to be separated in January owing to unconcilable differences, reportedly moved to Nashville. The musician remains in Brentwood, Tenn.
In October 2014, the couple married and separated, having daughters Florence, 6, and Josephine, 1.
While Accola and King continue to follow each other on Instagram, the guitarist has notably deleted their photographs, while keeping social media uploads with their daughters. (King is also the father of daughters Elise and Ava with ex-wife Julie.)
Accola has removed all of her Instagram comments last month. In the posts she has uploaded since, the actress has not seen her wedding ring.
Accola has since gone on to document life with Florence and Josephine by captioning her April Instagram return.
Last week, the former CW star took a trip to Europe with her friends and former costars Michael Trevino, Michael Malarkey, and David Anders.
My 35-year-old flair is inspired by Tuscan cottage, and Accola captioned photos on May 19 before going to Liverpool.
Nina Dobrev presented the pair at a Super Bowl party in February 2012. The rocker proposed to his then-partner in May of the following year.